11 AM in the morning and you can’t get it off ya

from Macklemore and Ryan Lewis (Ft. Allen Stone & Macklemore) – Neon Cathedral Lyrics on Rap Genius

Meaning

11 AM int the morning and you can’t get it off ya (referring to the fact that he can’t get the smell of vodka off of him)

coming to the preacher, but it’s like that pastor isn’t talkin'
Until the store opens and I can re-up on that doctrine.

Macklemore is talking about how the morning after drinking, he still can’t get the smell of vodka off of him—the bar/liquor store is his preacher, but is silent until the store opens up.

11am is also when some church services happen, if he smells like alcohol he would be less inclined to go to church disgraced and smelling of vodka. If he went to church smelling of vodka he’d have to face that others are judging him too.

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