When I shoot the moon,

from UGK (Ft. Outkast) – International Player's Anthem (I Choose You) Lyrics on Rap Genius

Meaning

In the game Hearts, “shooting the moon” where one tries to collect all the Hearts and the Queen of Spades. In André’s case, he has stolen the heart’s of all the women from his player days, and now he has his queen. A very difficult, risky move, because if you fall short you lose a lot of points; but then again so is marriage.

This keeps up the outer space theme from the last few lines. Shooting for the moon is also a phrase that simply describes having very high goals.

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