My mind is on Venus, but my neck is on Pluto

from Big Sean (Ft. Dwele) – Celebrity Lyrics on Rap Genius

Meaning

Women are from Venus, as well as Venus being the Godess of Love, Sex etc., Big Sean is talking about how he only thinks about women

Pluto is a giant ball of ice. His neck is iced out with jewelry.

by Venus he could also be saying his thoughts/mind frame is out of this world.

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